Record Information |
---|
Version | 1.0 |
---|
Creation Date | 2016-06-03 13:43:30 UTC |
---|
Update Date | 2016-11-09 01:23:25 UTC |
---|
Accession Number | CHEM045823 |
---|
Identification |
---|
Common Name | pyrrolysine |
---|
Class | Small Molecule |
---|
Description | A N(6)-acyl-L-lysine having (2R,3R)-3-methyl-3,4-dihydro-2H-pyrrol-2-ylcarbonyl as the N(6)-acyl group. |
---|
Contaminant Sources | |
---|
Contaminant Type | Not Available |
---|
Chemical Structure | |
---|
Synonyms | Value | Source |
---|
(2S)-2-Amino-6-[(2R,3R)-3-methyl-3,4-dihydro-2H-pyrrol-2-ylcarbonyl]aminohexanoic acid | ChEBI | Monomethylamine methyltransferase cofactor lysine adduct | ChEBI | N6-((2R,3R)-3-Methyl-3,4-dihydro-2H-pyrrol-2-ylcarbonyl)-L-lysine | ChEBI | N6-(4-Methyl-1,2-didehydropyrrolidine-5-carboxyl)-L-lysine | ChEBI | N6-(4-Methyl-delta-1-pyrroline-5-carboxyl)-L-lysine | ChEBI | Pyrrolysine | ChEBI | (2S)-2-Amino-6-[(2R,3R)-3-methyl-3,4-dihydro-2H-pyrrol-2-ylcarbonyl]aminohexanoate | Generator | N6-(4-Methyl-δ-1-pyrroline-5-carboxyl)-L-lysine | Generator | L-Pyrrolysine | MeSH | L-Pyrrolysine | MeSH | (2S)-2-Amino-6-({hydroxy[(2R,3R)-3-methyl-3,4-dihydro-2H-pyrrol-2-yl]methylidene}amino)hexanoate | Generator |
|
---|
Chemical Formula | C12H21N3O3 |
---|
Average Molecular Mass | 255.313 g/mol |
---|
Monoisotopic Mass | 255.158 g/mol |
---|
CAS Registry Number | 448235-52-7 |
---|
IUPAC Name | (2S)-2-amino-6-({hydroxy[(2R,3R)-3-methyl-3,4-dihydro-2H-pyrrol-2-yl]methylidene}amino)hexanoic acid |
---|
Traditional Name | pyrrolysine |
---|
SMILES | [H][C@](N)(CCCCN=C(O)[C@]1([H])N=CC[C@@]1([H])C)C(O)=O |
---|
InChI Identifier | InChI=1S/C12H21N3O3/c1-8-5-7-14-10(8)11(16)15-6-3-2-4-9(13)12(17)18/h7-10H,2-6,13H2,1H3,(H,15,16)(H,17,18)/t8-,9+,10-/m1/s1 |
---|
InChI Key | ZFOMKMMPBOQKMC-KXUCPTDWSA-N |
---|
Chemical Taxonomy |
---|
Description | belongs to the class of organic compounds known as l-alpha-amino acids. These are alpha amino acids which have the L-configuration of the alpha-carbon atom. |
---|
Kingdom | Organic compounds |
---|
Super Class | Organic acids and derivatives |
---|
Class | Carboxylic acids and derivatives |
---|
Sub Class | Amino acids, peptides, and analogues |
---|
Direct Parent | L-alpha-amino acids |
---|
Alternative Parents | |
---|
Substituents | - L-alpha-amino acid
- Pyrroline carboxylic acid or derivatives
- Medium-chain fatty acid
- Amino fatty acid
- Heterocyclic fatty acid
- Fatty acyl
- Fatty acid
- Pyrroline
- Carboxamide group
- Amino acid
- Secondary carboxylic acid amide
- Carboxylic acid
- Monocarboxylic acid or derivatives
- Azacycle
- Organoheterocyclic compound
- Propargyl-type 1,3-dipolar organic compound
- Organic 1,3-dipolar compound
- Primary amine
- Organooxygen compound
- Organonitrogen compound
- Amine
- Primary aliphatic amine
- Imine
- Organopnictogen compound
- Organic oxide
- Hydrocarbon derivative
- Organic nitrogen compound
- Carbonyl group
- Organic oxygen compound
- Aliphatic heteromonocyclic compound
|
---|
Molecular Framework | Aliphatic heteromonocyclic compounds |
---|
External Descriptors | |
---|
Biological Properties |
---|
Status | Detected and Not Quantified |
---|
Origin | Not Available |
---|
Cellular Locations | Not Available |
---|
Biofluid Locations | Not Available |
---|
Tissue Locations | Not Available |
---|
Pathways | Not Available |
---|
Applications | Not Available |
---|
Biological Roles | Not Available |
---|
Chemical Roles | Not Available |
---|
Physical Properties |
---|
State | Not Available |
---|
Appearance | Not Available |
---|
Experimental Properties | Property | Value |
---|
Melting Point | Not Available | Boiling Point | Not Available | Solubility | Not Available |
|
---|
Predicted Properties | |
---|
Spectra |
---|
Spectra | Spectrum Type | Description | Splash Key | View |
---|
Predicted GC-MS | Predicted GC-MS Spectrum - GC-MS (TMS_2_2) - 70eV, Positive | Not Available | Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 10V, Positive | splash10-08gs-3590000000-5a5b6bf2a8269d308d7c | Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 20V, Positive | splash10-000t-9610000000-a22a9fede9bbbe4966f1 | Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 40V, Positive | splash10-053r-9100000000-409db8753a6081aab3f6 | Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 10V, Negative | splash10-0udi-0190000000-255a0359c5c313d6babf | Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 20V, Negative | splash10-0h11-3960000000-0399ae9e930b64052efd | Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - 40V, Negative | splash10-001i-9300000000-6e0685cc0fe000454ea2 | Spectrum |
|
---|
Toxicity Profile |
---|
Route of Exposure | Not Available |
---|
Mechanism of Toxicity | Not Available |
---|
Metabolism | Not Available |
---|
Toxicity Values | Not Available |
---|
Lethal Dose | Not Available |
---|
Carcinogenicity (IARC Classification) | Not Available |
---|
Uses/Sources | Not Available |
---|
Minimum Risk Level | Not Available |
---|
Health Effects | Not Available |
---|
Symptoms | Not Available |
---|
Treatment | Not Available |
---|
Concentrations |
---|
| Not Available |
---|
External Links |
---|
DrugBank ID | Not Available |
---|
HMDB ID | Not Available |
---|
FooDB ID | Not Available |
---|
Phenol Explorer ID | Not Available |
---|
KNApSAcK ID | Not Available |
---|
BiGG ID | Not Available |
---|
BioCyc ID | CPD-3321 |
---|
METLIN ID | Not Available |
---|
PDB ID | Not Available |
---|
Wikipedia Link | Pyrrolysine |
---|
Chemspider ID | Not Available |
---|
ChEBI ID | 21860 |
---|
PubChem Compound ID | 5460671 |
---|
Kegg Compound ID | C16138 |
---|
YMDB ID | Not Available |
---|
ECMDB ID | Not Available |
---|
References |
---|
Synthesis Reference | Not Available |
---|
MSDS | Not Available |
---|
General References | |
---|